CONTROL OF CARBENOID REACTIVITY THROUGH NEIGHBORING GROUP PARTICIPATION

Authors
DAVIES HML MATASI JJ THORNLEY C
Citation
Hml. Davies et al., CONTROL OF CARBENOID REACTIVITY THROUGH NEIGHBORING GROUP PARTICIPATION, Tetrahedron letters, 36(40), 1995, pp. 7205-7208
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
40
Year of publication
1995
Pages
7205 - 7208
Database
ISI
SICI code
0040-4039(1995)36:40<7205:COCRTN>2.0.ZU;2-P
Abstract
Product distribution in the rhodium(II) carboxylate catalyzed decompos ition of vinyldiazomethanes in the presence of N-(BOC)pyrroles can be controlled through stabilization of the vinylcarbenoid intermediates b y neighboring group participation.