TI(IV),ZR(IV) AND TH(IV) SORPTIONON 1(4'-AZOBENZYLCELZULOSE)-2-NAPHTOL - THERMOGRAVIMETRIC CHARACTERIZATION

Authors
ONOFREI T ODOCHIAN L DULMAN V IRIMIA G
Citation
T. Onofrei et al., TI(IV),ZR(IV) AND TH(IV) SORPTIONON 1(4'-AZOBENZYLCELZULOSE)-2-NAPHTOL - THERMOGRAVIMETRIC CHARACTERIZATION, Cellulose Chemistry and Technology, 29(2), 1995, pp. 135-142
Citations number
15
Categorie Soggetti
Materials Science, Paper & Wood
Journal title
Cellulose Chemistry and Technology → ACNP
ISSN journal
05769787
Volume
29
Issue
2
Year of publication
1995
Pages
135 - 142
Database
ISI
SICI code
0576-9787(1995)29:2<135:TATS1>2.0.ZU;2-P
Abstract
1(4'-azobenzylcellulose)-2-naphtol was analyzed thermogravimetrically under dynamic conditions of temperature before and after sorption of T i(IV), Zr(IV) and Th(IV). The results obtained plead for a mechanism o f differential chemosorption of Ti(IV), Zr(Ir) and Th(IV) on the sorbe nt considered for the study, which is superposed on physical sorption. Strength of the sorbent-metal links depends on the nature of the sorb ed element, which is also confirmed by the existence of a real effect of compensation, expressed by equation lnA = 0.2E-1.