D. Stewart et al., BLACKCURRENT STEMS - A NOVEL NON-TREE FIBER FOR THE PRODUCTION OF PULP AND PAPER, Cellulose Chemistry and Technology, 29(2), 1995, pp. 203-214
Debarked sterns of blackcurrant (Ribes nigrum L.; cv. Ben alder) were
hammer-milled and extracted with water (70 degrees) and diethyl ether.
The residue was subjected to alkaline extractions with increasing con
centrations of aqueous NaOH and chlorite delignification. Analysis of
the neutral sugar, lignin and uronic acid contents of the residues and
extracts indicated that blackcurrant stem should be considered as a t
ypical hardwood. The 0.1 M and 1.0M NaOH extracts provided both hemice
llulose (H/C) A and a H/C B fraction, while the 4.5M NaOH extract only
yielded the latter. The principal polysaccharides in all these fracti
ons mere glucuronoxylans. These were present at higher concentrations
in each H/C B fraction than the corresponding H/C A fraction. Other po
lysaccharides present mere arabinoglucuronoxylan, glucomannan, mannan
and galactan. The extracted lignin contents were greatest in the H/C A
fractions. Tile effects of chlorite delignification mere largely conf
ined to a reduction in the residual lignin content by c. 94%. This was
confirmed by FT-IR spectroscopy. Four distinct cell types were found
in blackcurrent stems; tracheids, libriform fibres, vessel elements an
d ray parenchyma cells, These cell types are also present in a typical
hardwood, although their dimensions were smaller. The results of the
study suggest that blackcurrant stem fibres ha-e the potential to he u
sed along with existing mood-based fibres in the production of pulp fo
r paper manufacture.