SYNTHESIS OF NEW ENANTIOPURE GAMMA-AMINOALCOHOLS - THEIR USE AS CATALYSTS IN THE ALKYLATION OF BENZALDEHYDE BY DIETHYLZINC

Authors
CICCHI S CREA S GOTI A BRANDI A
Citation
S. Cicchi et al., SYNTHESIS OF NEW ENANTIOPURE GAMMA-AMINOALCOHOLS - THEIR USE AS CATALYSTS IN THE ALKYLATION OF BENZALDEHYDE BY DIETHYLZINC, Tetrahedron : asymmetry, 8(2), 1997, pp. 293-301
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
2
Year of publication
1997
Pages
293 - 301
Database
ISI
SICI code
0957-4166(1997)8:2<293:SONEG->2.0.ZU;2-Z
Abstract
The straightforward synthesis of new enantiopure gamma-aminoalcohols t hrough 1,3-dipolar cycloadditon to a chiral cyclic nitrone derived fro m L-malic acid is described. Results of the application of these compo unds as chiral catalysts in the alkylation of benzaldehyde with diethy lzinc are also reported. (C) 1997 Elsevier Science Ltd.