Small-angle X-ray scattering studies have been performed on a series o
f four a-Si:C:H alloys, prepared by rf glow discharge decomposition of
varying proportions of propane and silane, in an attempt to elucidate
their mesoscopic structure. The observed broad scattering peak has be
en interpreted as originating from irregular, elongated voids with a r
epeat distance of about 20 Angstrom and correlation length of about 25
Angstrom. The implications of this result in explaining the photo-oxi
dation properties of the material are also discussed.