Evidence for the existence of quantum size effects ill amorphous diamo
nd-like carbon superlattice structures from optical and electronic mea
surements together with theoretical predictions are reported. A 'blue
shift' in the optical gap is shown to occur with decreasing well width
from which an effective mass for the electrons (and holes) is obtaine
d. Regions of negative differential resistance are observed in the cur
rent-voltage characteristics at temperatures ranging from 4-300 K. Dar
k conductivity studies point to a current that is dominated by a tunne
lling component rather than thermal carrier emission over the barrier
layers of the superlattice. Activation energy studies show an increase
in the activation energy with decreasing well width, in keeping with
the observed optical 'blue shift'. The voltage range over which negati
ve differential resistance is measured agrees well with resonant tunne
lling predictions.