A new family of high-temperature, oxidation-resistant, ceramic composi
tes, with (La)-monazite (LaPO4) serving as a weakly bonded interphase,
is proposed. Monazite is stable and phase-compatible with alumina at
temperatures at least as high as 1750 degrees C in air. Especially imp
ortant for use in high-toughness composites, the monazite-alumina inte
rface is shown to be sufficiently weak that interfacial debonding prev
ents cracks from growing from monazite into alumina. Observations of f
racture responses of fibrous and laminar reinforcements are presented.