T. Mulja et al., THE RARE-ELEMENT-ENRICHED MONZOGRANITE-PEGMATITE-QUARTZ VEIN SYSTEMS IN THE PREISSAC-LACORNE BATHOLITH, QUEBEC .1. GEOLOGY AND MINERALOGY, Canadian Mineralogist, 33, 1995, pp. 793-815
The monzogranitic plutons in the Preissac-Lacorne batholith, Quebec, i
n the Abitibi Greenstone Belt of the Superior Province, display geolog
ical and mineralogical features that resemble idealized zoned intrusio
ns and associated rare-element pegmatites and quartz veins. The zoning
comprises biotite, two-mica, and muscovite monzogranites; the mineral
ization in pegmatite-poor plutons is dominated by molybdenite-bearing
quartz veins, which are spatially related to the more evolved rocks (i
.e., muscovite-bearing monzogranite). In contrast, pegmatite-rich plut
ons are surrounded by rare-element pegmatites, which vary systematical
ly with distance from the plutons from beryl-bearing through spodumene
-beryl-bearing to spodumene-bearing. In addition, Mo-bearing albitite
dikes and quartz veins occur beyond the spodumene pegmatites. Mineralo
gical changes from biotite to muscovite monzogranite are characterized
by a decrease in the abundance of oligoclase, biotite, magnetite, mon
azite, apatite, and zircon, and an increase in the abundance of albite
, muscovite and garnet. The mineralogical trend continues into the peg
matites, which are composed of albite, K-feldspar, quartz, muscovite (
biotite is absent), garnet, beryl, spodumene, molybdenite, and columbi
te-tantalite. The major-element chemistry of the rock-forming minerals
changes progressively from biotite through two-mica to muscovite monz
ogranite; plagioclase compositions vary from An(13-17) to An(6), and t
he Fe/(Fe + Mg) of biotite and muscovite increases from 0.7 to 0.85 an
d from 0.65 to 0.85, respectively. This mineral-chemical evolution ext
ends into the pegmatites; the plagioclase in these rocks is almost pur
e albite (An(1-5)), and muscovite is lower in Fe/(Fe + Mg) and richer
in Al than that in the muscovite monzogranite. Concentrations of Cs, T
a, and Rb in muscovite increase, whereas that of Sc decreases, from th
e muscovite monzogranite to the rare-metal pegmatites. The systematic
mineralogical evolution and mineral-chemical trends, and the field rel
ationships of the monzogranites, are intrepreted to indicate that the
various subtypes of monzogranite were produced mainly by fractional cr
ystallization of biotite monzogranitic magma. Further differentiation
of the fractionated monzogranitic melts produced rare-element pegmatit
es.