CARBON-DIOXIDE DISPOSAL IN CARBONATE MINERALS

Citation
Ks. Lackner et al., CARBON-DIOXIDE DISPOSAL IN CARBONATE MINERALS, Energy, 20(11), 1995, pp. 1153-1170
Citations number
47
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
EnergyACNP
ISSN journal
03605442
Volume
20
Issue
11
Year of publication
1995
Pages
1153 - 1170
Database
ISI
SICI code
0360-5442(1995)20:11<1153:CDICM>2.0.ZU;2-P
Abstract
We introduce a safe and permanent method of CO2 disposal based on comb ining CO2. chemically with abundant raw materials to form stable carbo nate minerals. Substantial heat is liberated in the overall chemical r eaction so that cost will be determined by the simplicity and speed of the reaction rather than the cost of energy. Preliminary investigatio ns have been conducted on two types of processes, involving either dir ect carbonation of minerals at high temperature or processing in aqueo us solution. Promising raw materials are identified in both cases. For aqueous processing, a chemical cycle employing well-known reactions i s proposed for digesting and carbonating the raw material. Cost estima tes, based on comparison with standard industrial and mining practice, are encouraging. Necessary raw materials are surveyed and vast quanti ties are found to be easily accessible. Amounts are sufficient to allo w utilization of the large known fossil-fuel reserves while avoiding b uild-up of atmospheric CO2.