In the past metal carbon layers gained more and more importance in tri
bological applications. Especially those applications without lubricat
ions as food biotechnology or medical industrial are of high interest
for hard metal-carbon layers. Special characteristics of different arc
metal, doped hard carbon layers will be reported with respect to thei
r wear and corrosion behaviour as well as with respect to thermodynami
cal constitution In addition to the laboratory investigations, pratica
l long term results on plunger, clean fuel pumps and bearings will be
discussed. The different metal species in the hard carbon influence th
e characteristics in different ways. Chromium reduces the corrosion pr
otection dramatically but increases the layers wear resistance. Alloy
of titanium tungsten result in the lowest friction coefficient with le
ss dependancy on moisture. Niobium leads to layers with the lowest har
dness but with a good transfer behaviour.