THERMAL RETROCYCLOADDITION OF OVERCROWDED GERMIRENES - A NEW METHOD FOR THE GENERATION OF GERMYLENES

Authors
TOKITOH N KISHIKAWA K MATSUMOTO T OKAZAKI R
Citation
N. Tokitoh et al., THERMAL RETROCYCLOADDITION OF OVERCROWDED GERMIRENES - A NEW METHOD FOR THE GENERATION OF GERMYLENES, Chemistry Letters, (9), 1995, pp. 827-828
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1995
Pages
827 - 828
Database
ISI
SICI code
0366-7022(1995):9<827:TROOG->2.0.ZU;2-Z
Abstract
Thermolysis of overcrowded 2,3-diphenylgermirenes bearing bulky substi tuents on the germanium atom in benzene affords the corresponding kine tically stabilized germylenes, the efficient formation of which is evi denced by the trapping experiments with 2,3-dimethyl-1,3-butadiene. Th is provides a new and mild method for the generation of germylenes.