INVESTIGATION OF CHEMICAL AND SPIN DYNAMICS IN MICELLIZED RADICAL PAIRS BY TIME-RESOLVED STIMULATED NUCLEAR-POLARIZATION - THEORY AND EXPERIMENT

Authors
PARNACHEV AP BAGRYANSKAYA EG TARASOV VF LUKZEN NN SAGDEEV RZ
Citation
Ap. Parnachev et al., INVESTIGATION OF CHEMICAL AND SPIN DYNAMICS IN MICELLIZED RADICAL PAIRS BY TIME-RESOLVED STIMULATED NUCLEAR-POLARIZATION - THEORY AND EXPERIMENT, Chemical physics letters, 244(3-4), 1995, pp. 245-251
Citations number
34
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
244
Issue
3-4
Year of publication
1995
Pages
245 - 251
Database
ISI
SICI code
0009-2614(1995)244:3-4<245:IOCASD>2.0.ZU;2-0
Abstract
A numerical solution of the stochastic Liouville equation for a micror eactor model is applied to the theoretical treatment of time-resolved stimulated nuclear polarization data, obtained during the investigatio n of micellized radical pairs, conducted in two different modes, Escap e rate constants and relaxation parameters of radical pairs formed in the photolysis of methyldeoxybenzoin and benzoin in alkyl sulfate mice lles of different sizes have been obtained. The conditions of the S-T- 0 quantum oscillations in SNP kinetics have been determined.