The effect of kind and concentration of alkali on the gelatinization o
f maize, rice and wheat starches were thoroughly investigated. No gela
tinization could be observed on using the carbonate and/or bicarbonate
of sodium and potassium even on using their saturated solutions, whil
e both sodium and potassium hydroxides undergo gelatinization. Gelatin
ization of starch occurs immediately at a concentration of sodium hydr
oxide of 1.2%, while clear gelatinized pastes could be obtained at 4%
or more. Infra-red spectra of maize and rice starches before and after
alkali treatment reveal that treatment of starch with sodium hydroxid
e is accompanied by some physicochemical changes in the structure of s
tarch. The theological properties as well as the apparent viscosity of
the gelatinized starch pastes depend on the kind of starch as well as
the nature and concentration of alkali used.