CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC TECHNETIUM TRICARBONYL IODIDE [TC(CO)(3)I](4)

Authors
GRIGOREV MS MIROSLAVOV AE SIDORENKO GV STRUCHKOV YT SUGLOBOV DN
Citation
Ms. Grigorev et al., CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC TECHNETIUM TRICARBONYL IODIDE [TC(CO)(3)I](4), Radiochemistry, 37(3), 1995, pp. 177-179
Citations number
5
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
37
Issue
3
Year of publication
1995
Pages
177 - 179
Database
ISI
SICI code
1066-3622(1995)37:3<177:CAMOTT>2.0.ZU;2-Z
Abstract
The structure of [Tc(CO)(3)I](4) has been studied by single-crystal X- ray diffraction. Crystal data: monoclinic, a = 18.125(12), b = 9.741(6 ), c = 16.577(9) Angstrom, beta = 118.50(4)degrees, V = 2572(3) Angstr om(3), space group C2/c, Z = 4, d(calc) = 3.191 g cm(-3), mu(MoKa) = 6 7 cm(-1). The crystal structure consists of isolated tetrameric molecu les [Tc(CO)(3)I](4) having a cubane-like structure. The Tc(CO)(3) moie ties are linked via bridging iodide ligands.