MECHANOEMISSION AND MECHANOCHEMISTRY OF T HE MOLECULAR ORGANIC-CRYSTALS

Citation
Ea. Varentsov et Ya. Khrustalev, MECHANOEMISSION AND MECHANOCHEMISTRY OF T HE MOLECULAR ORGANIC-CRYSTALS, Uspehi himii, 64(8), 1995, pp. 834-849
Citations number
134
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00421308
Volume
64
Issue
8
Year of publication
1995
Pages
834 - 849
Database
ISI
SICI code
0042-1308(1995)64:8<834:MAMOTH>2.0.ZU;2-8
Abstract
Results of the study emission phenomena and chemical processes in the organic molecular crystals, rapidly decomposing exothermically at the mechanical actions art rewieved. The influence of the nature, and the gase pressure of the reaction system on the initiation probability of the mechanochemical decomposition of the single crystal is discussed. The modern concepts of the fast reactions initiativ in organic crystal are analyzed. The general scheme of the electrophysical phenomena and chemical transformation at the mechanical action on the sulids is sug gested.