HALOGENATION OF 1-TRIFLUOROMETHYL ENAMINES - A NEW AND EFFICIENT SYNTHESIS OF ALPHA-BROMO-TRIFLUOROMETHYL AND ALPHA-IODO-TRIFLUOROMETHYL KETONES

Authors
BEGUE JP BONNETDELPON D BOUVET D ROCK MH
Citation
Jp. Begue et al., HALOGENATION OF 1-TRIFLUOROMETHYL ENAMINES - A NEW AND EFFICIENT SYNTHESIS OF ALPHA-BROMO-TRIFLUOROMETHYL AND ALPHA-IODO-TRIFLUOROMETHYL KETONES, Journal of fluorine chemistry, 80(1), 1996, pp. 17-20
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
80
Issue
1
Year of publication
1996
Pages
17 - 20
Database
ISI
SICI code
0022-1139(1996)80:1<17:HO1E-A>2.0.ZU;2-G
Abstract
Treatment of the 1-trifluoromethyl enamines 1a-d with bromine or iodin e results in the formation of the corresponding iminium salts. Treatme nt of any of these salts with methanol results in the formation of the corresponding alpha-halo-trifluoromethyl ketones.