M. Ozaki et al., ION COMPLEX FILMS OF POLY(BUTYLENEVIOLOGEN) AND AN ANIONIC AMPHIPHILE- SALT CONCENTRATION-DEPENDENT STRUCTURE AND ELECTROCHEMISTRY, Russian journal of electrochemistry, 31(9), 1995, pp. 896-899
The electrochemical behavior of ion complex films consisting of poly(b
utyleneviologen) and an anionic amphiphile was studied in NaClO4 aqueo
us solutions using a quartz crystal resonator, The behavior as well as
the visible spectrum of the reduced film changed largely at a NaClO4
concentration range between 0.05 and 0.1 M, indicating that the film s
tructure changed. The microstructures of the reduced and oxidized film
s at low and high concentration regions were discussed.