STUDY ON CATALYTIC EFFECT OF COPPER(II) COMPLEX ON 1,10-PHENANTHROLINE-H2O2-CTMAB CHEMILUMINESCENCE REACTION AND ITS ANALYTICAL APPLICATIONS

Authors
LI ZP DAI LT ZHANG ZJ
Citation
Zp. Li et al., STUDY ON CATALYTIC EFFECT OF COPPER(II) COMPLEX ON 1,10-PHENANTHROLINE-H2O2-CTMAB CHEMILUMINESCENCE REACTION AND ITS ANALYTICAL APPLICATIONS, Microchemical journal, 52(2), 1995, pp. 208-215
Citations number
16
Categorie Soggetti
Chemistry Analytical
Journal title
Microchemical journal → ACNP
ISSN journal
0026265X
Volume
52
Issue
2
Year of publication
1995
Pages
208 - 215
Database
ISI
SICI code
0026-265X(1995)52:2<208:SOCEOC>2.0.ZU;2-N
Abstract
Through our flow injection analysis experiments, we discovered that an unsaturated complex of Cu(II) and organic ligand had a strong catalyt ic effect on 1.10-phenanthroline-H2O2-CTMAB chemiluminescence reaction . Based on this mechanism, the new flow injection analysis methods for detection of some biological ligands were established. Detection limi ts are in the range of 2.7-90 pmol for amino acids, polyamines, and sa licylic acids. (C) 1995 Academic Press, Inc.