B. Baker et al., SOFT CHEMICAL SYNTHESIS OF A HIGH-PRESSURE PHASE OF MOLYBDENUM TRIOXIDE - MOO3-II, Journal of solid state chemistry, 119(1), 1995, pp. 199-202
Topotactic dehydration of either the white molybdenum trioxide monohyd
rate, MoO3 . H2O, or the hemihydrate, MoO3 . 1/2H(2)O, provides a conv
enient synthetic route to a high-pressure phase of molybdenum trioxide
, MoO3-II. The structural filiations between the various molybdenum tr
ioxide and trioxide hydrate phases are delineated, and simple mechanis
tic models for the transformations are proposed. (C) 1995 Academic Pre
ss, Inc.