SOFT CHEMICAL SYNTHESIS OF A HIGH-PRESSURE PHASE OF MOLYBDENUM TRIOXIDE - MOO3-II

Authors
BAKER B FEIST TP MCCARRON EM
Citation
B. Baker et al., SOFT CHEMICAL SYNTHESIS OF A HIGH-PRESSURE PHASE OF MOLYBDENUM TRIOXIDE - MOO3-II, Journal of solid state chemistry, 119(1), 1995, pp. 199-202
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
119
Issue
1
Year of publication
1995
Pages
199 - 202
Database
ISI
SICI code
0022-4596(1995)119:1<199:SCSOAH>2.0.ZU;2-Q
Abstract
Topotactic dehydration of either the white molybdenum trioxide monohyd rate, MoO3 . H2O, or the hemihydrate, MoO3 . 1/2H(2)O, provides a conv enient synthetic route to a high-pressure phase of molybdenum trioxide , MoO3-II. The structural filiations between the various molybdenum tr ioxide and trioxide hydrate phases are delineated, and simple mechanis tic models for the transformations are proposed. (C) 1995 Academic Pre ss, Inc.