Yy. Xia et al., DIFFERENCES IN ELECTROCHEMICAL-BEHAVIOR OF LIMN2O4 AND LI1-V LI-CELL CATHODES(XMN3O4 AS 4), Journal of solid state chemistry, 119(1), 1995, pp. 216-218
Stoichiometric spinel LiMn2O4 delivers a large initial capacity of 140
mA hr/g and has unstable rechargeability. The capacity fading of the
cell on cycling occurs only in the higher charge voltage range of x <
0.45 in LixMn2O4. Nonstoichiometric spinel Li1+xMn2O4 has a slightly l
ower capacity of 110 mA hr/g and has an excellent cycling behavior. (C
) 1995 Academic Press, Inc.