NE)(IODO)(METHYL)(THIOACETYLACETONATO)IRIDIUM(III)

Authors
TERBLANS YM BASSON SS PURCELL W LAMPRECHT GJ
Citation
Ym. Terblans et al., NE)(IODO)(METHYL)(THIOACETYLACETONATO)IRIDIUM(III), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1748-1750
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
9
Pages
1748 - 1750
Database
ISI
SICI code
0108-2701(1995)51:<1748:N>2.0.ZU;2-5
Abstract
The structure determination of the title complex, [Ir(C5H7OS)(CH3)(I)( C8H12)], revealed that the oxidative addition of iodomethane to (eta(4 ) 1,5-cyclooctadiene)(thioacetylacetonato)iridium(I) results in the fo rmation of the trans isomer. The deviation of the I-Ir-CH3 angle [156. 1(3)degrees] from linearity is attributed to steric repulsion between the CH3 group or I atom and the olefinic H atoms.