XY-4-METHOXG-N-METHYLTHIOBENZAMIDO-O,S)-IRIDIUM(I)

Authors
THERON M BASSON SS PURCELL W
Citation
M. Theron et al., XY-4-METHOXG-N-METHYLTHIOBENZAMIDO-O,S)-IRIDIUM(I), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1750-1752
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
9
Pages
1750 - 1752
Database
ISI
SICI code
0108-2701(1995)51:<1750:X>2.0.ZU;2-Z
Abstract
The average olefinic carbon bond length of 1.52 (2) Angstrom in the cy clooctadiene ligand of [Ir(C9H10NO2S)(C8H12)] is surprisingly long for an olefinic bond (1.34-1.43 Angstrom) and corresponds more closely to an aliphatic carbon bond length (1.54 Angstrom) [Henrici-Olive & Oliv e (1977). Coordination and Catalysis, pp. 110-114; International Table s for X-ray Crystallography, 1992, Vol. C, Table 9.5.1.1]. The Ir-S an d Ir-O bond distances of 2.279(3) and 2.030(7) Angstrom, respectively, are normal for this kind of complex [Botha, Basson & Leipoldt (1987). Inorg. Chim. Acta, 126, 25-28].