MEASUREMENT AND CORRELATION OF VAPOR-LIQUID-EQUILIBRIA IN POLYMER-SOLUTIONS CONTAINING POLYSTYRENE WITH POLYMER ASOG

Authors
CHOI JS TOCHIGI K KOJIMA K
Citation
Js. Choi et al., MEASUREMENT AND CORRELATION OF VAPOR-LIQUID-EQUILIBRIA IN POLYMER-SOLUTIONS CONTAINING POLYSTYRENE WITH POLYMER ASOG, Fluid phase equilibria, 111(1), 1995, pp. 143-156
Citations number
22
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
Fluid phase equilibria → ACNP
ISSN journal
03783812
Volume
111
Issue
1
Year of publication
1995
Pages
143 - 156
Database
ISI
SICI code
0378-3812(1995)111:1<143:MACOVI>2.0.ZU;2-A
Abstract
A gas chromatographic method is used to measure the activities of solv ents which have a range of finite concentrations in polymer solutions. Experimental data are presented for 8 binary solvent/polystyrene syst ems at 393.15 and 423.15 K. The polymer ASOG is proposed to be correla ted with the activities of solvents in polymer solutions, and consists of the original ASOG and the empirical modification of free volume. F or 8 binary solvent/polystyrene systems containing nonpolar and modera tely polar solvents, the polymer ASOG was successful to correlate with experimental data within the range of 1% error.