SOAP-FREE EMULSION POLYMERIZATION OF VINYL MONOMERS IN THE PRESENCE OF POLY(N-ACETYL IMINOETHYLENE) MACROAZOINITIATORS

Citation
Ci. Simionescu et al., SOAP-FREE EMULSION POLYMERIZATION OF VINYL MONOMERS IN THE PRESENCE OF POLY(N-ACETYL IMINOETHYLENE) MACROAZOINITIATORS, Pure and applied chemistry, A32, 1995, pp. 1095-1101
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00334545
Volume
A32
Year of publication
1995
Supplement
7
Pages
1095 - 1101
Database
ISI
SICI code
0033-4545(1995)A32:<1095:SEPOVM>2.0.ZU;2-L
Abstract
The soap-free emulsion polymerization of some hydrophobic vinyl monome rs (styrene, methyl methacrylate, n-butyl methacrylate) in the presenc e of water soluble poly(N-acetyl iminoethylene) macroazoinitiators was investigated. The polymerization system features are controlled by th e nature and concentration of both monomer and macroinitiator. The res ulting block copolymers were proved to act as emulsifiers in inverse e mulsion polymerizations.