1,12-DIMETHYL[1.1]FERROCENOPHANE, AN ORGANOMETALLIC CYCLOHEXANE ANALOG WITH EXTRAORDINARY FLEXIBILITY - MOLECULAR-STRUCTURE OF A 3RD ISOMER, EXO,ENDO,SYN-1,12-DIMETHYL[1.1]FERROCENOPHANE

Citation
Jm. Lowendahl et M. Hakansson, 1,12-DIMETHYL[1.1]FERROCENOPHANE, AN ORGANOMETALLIC CYCLOHEXANE ANALOG WITH EXTRAORDINARY FLEXIBILITY - MOLECULAR-STRUCTURE OF A 3RD ISOMER, EXO,ENDO,SYN-1,12-DIMETHYL[1.1]FERROCENOPHANE, Organometallics, 14(10), 1995, pp. 4736-4741
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
14
Issue
10
Year of publication
1995
Pages
4736 - 4741
Database
ISI
SICI code
0276-7333(1995)14:10<4736:1AOCA>2.0.ZU;2-W
Abstract
A third isomer of 1,12-dimethyl[1.1]ferroeenophane (DMFCP), i.e. exo,e ndo,syn-1,12- dimethyl[1.1]ferrocenophane (1c), has been isolated and structurally characterized by X-ray diffraction. The conformational pr operties of 1c and other [1.1]ferrocenophanes are discussed and compar ed with those of cyclohexanes.