N,N-BIS(TRIMETHYLSILYL)ALKENESULFENAMIDES - SYNTHESIS AND TRANSAMINATIONS VIA S-ALKENYLTHIOPHTHALIMIDES - A GENERAL-ROUTE TO ALKENESULFENAMIDES AND ALKENESULFONAMIDES
Al. Schwan et Md. Refvik, N,N-BIS(TRIMETHYLSILYL)ALKENESULFENAMIDES - SYNTHESIS AND TRANSAMINATIONS VIA S-ALKENYLTHIOPHTHALIMIDES - A GENERAL-ROUTE TO ALKENESULFENAMIDES AND ALKENESULFONAMIDES, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 1949-1950
N,N-bis(Trimethylsilyl)alkenesulfenamide 3, prepared by the reaction o
f trans-alkenesulfenates with TMSCI and LiHMDS, are modified to their
corresponding S-alkenylthiophthalimides 6 which are then converted to
alkenesulfenamides 7 bearing more general nitrogen functionality.