N,N-BIS(TRIMETHYLSILYL)ALKENESULFENAMIDES - SYNTHESIS AND TRANSAMINATIONS VIA S-ALKENYLTHIOPHTHALIMIDES - A GENERAL-ROUTE TO ALKENESULFENAMIDES AND ALKENESULFONAMIDES

Citation
Al. Schwan et Md. Refvik, N,N-BIS(TRIMETHYLSILYL)ALKENESULFENAMIDES - SYNTHESIS AND TRANSAMINATIONS VIA S-ALKENYLTHIOPHTHALIMIDES - A GENERAL-ROUTE TO ALKENESULFENAMIDES AND ALKENESULFONAMIDES, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 1949-1950
Citations number
25
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
19
Year of publication
1995
Pages
1949 - 1950
Database
ISI
SICI code
0022-4936(1995):19<1949:N-SAT>2.0.ZU;2-9
Abstract
N,N-bis(Trimethylsilyl)alkenesulfenamide 3, prepared by the reaction o f trans-alkenesulfenates with TMSCI and LiHMDS, are modified to their corresponding S-alkenylthiophthalimides 6 which are then converted to alkenesulfenamides 7 bearing more general nitrogen functionality.