N. Masciocchi et al., COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 1955-1956
[{Pd(dmpz)(2)(Hdmpz)(2)}(2)] (Hdmpz = 3,5-dimethylpyrazole) reacts wit
h COS, both in solution and in the solid state, affording [Pd{SC(O)dmp
z}(2)] and [{Pd(dmpz)(2)(Hdmpz)(2)}2]. COS, respectively; the structur
e of the latter is determined by ab initio methods from conventional X
-ray powder diffraction data only.