COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION

Citation
N. Masciocchi et al., COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 1955-1956
Citations number
11
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
19
Year of publication
1995
Pages
1955 - 1956
Database
ISI
SICI code
0022-4936(1995):19<1955:CTBPP->2.0.ZU;2-X
Abstract
[{Pd(dmpz)(2)(Hdmpz)(2)}(2)] (Hdmpz = 3,5-dimethylpyrazole) reacts wit h COS, both in solution and in the solid state, affording [Pd{SC(O)dmp z}(2)] and [{Pd(dmpz)(2)(Hdmpz)(2)}2]. COS, respectively; the structur e of the latter is determined by ab initio methods from conventional X -ray powder diffraction data only.