MIXED ORGANOZINC-DIORGANOPHOSPHIDE COMPLEX CONTAINING PROTIC PHOSPHINE-LIGANDS BONDED TO ZINC

Citation
Mg. Davidson et al., MIXED ORGANOZINC-DIORGANOPHOSPHIDE COMPLEX CONTAINING PROTIC PHOSPHINE-LIGANDS BONDED TO ZINC, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 1989-1990
Citations number
9
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
19
Year of publication
1995
Pages
1989 - 1990
Database
ISI
SICI code
0022-4936(1995):19<1989:MOCCPP>2.0.ZU;2-M
Abstract
Metallation of diphenylphosphine with ZnEt(2) (5:3 equiv.) in thf prod uces {[EtZn(u-PPh(2))](3) .(HPPh(2))(2) . thf} 1, which is shown by X- ray crystallography to have a Zn3P3 core in which Ph(2)PH ligands act as donors to two of the zinc centres.