A DIRECT INTRODUCTION OF PERFLUOROOCTYL GROUP INTO CYCLOALKANES USINGTHE PHOTOLYSIS OF PERFLUOROAZOOCTANE UPON 185-NM IRRADIATION

Authors
NAKAMURA T YABE A
Citation
T. Nakamura et A. Yabe, A DIRECT INTRODUCTION OF PERFLUOROOCTYL GROUP INTO CYCLOALKANES USINGTHE PHOTOLYSIS OF PERFLUOROAZOOCTANE UPON 185-NM IRRADIATION, Journal of the Chemical Society, Chemical Communications, (19), 1995, pp. 2027-2028
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
19
Year of publication
1995
Pages
2027 - 2028
Database
ISI
SICI code
0022-4936(1995):19<2027:ADIOPG>2.0.ZU;2-4
Abstract
Perfluorooctyl-substituted cycloalkanes are prepared directly by photo lysis of perfluoroazooctane in cycloalkanes upon 185 nm irradiation; a plausible mechanism is discussed on the basis of the time-course, qua ntum yield, and light intensity dependence during this photoreaction.