We investigate diffusion-induced instabilities of phase waves in one s
patial dimension for a two-variable model of the Belousov-Zhabotinsky
reaction. We use as initial conditions small-amplitude phase waves whi
ch exist in the parametric range between a canard point and a supercri
tical Hopf bifurcation point. Closer to the canard point, the instabil
ity leads to initiation of trigger waves, usually at the zero flux bou
ndary. Such induced trigger waves reflect from the boundary, and when
they collide, a new trigger wave emerges at the location of the collis
ion. When the parameters are chosen nearer to the Hopf point, the phas
e waves lose their regular pattern and become uncorrelated. Very close
to the Hopf point, diffusion alters the phase wave profile into small
-amplitude synchronized bulk oscillations. Different types of spatiote
mporal behavior are observed when the wavelength of the phase waves, t
he overall size of the system, or the diffusion coefficients are chang
ed. Comparison of the behavior near a canard and near a subcritical Ho
pf bifurcation shows that in the former case trigger waves can be init
iated at all points of the excitable medium, whereas in the latter cas
e trigger waves are generated only at the boundary.