AN EXACTLY SOLVABLE MODEL OF THE DIPOLE-DIPOLE RELAXATION OF THE ELECTRON SPINS OF MICELLIZED RADICAL PAIRS

Authors
ISAKOV SV LUKZEN NN MOROZOV VA SAGDEEV RZ
Citation
Sv. Isakov et al., AN EXACTLY SOLVABLE MODEL OF THE DIPOLE-DIPOLE RELAXATION OF THE ELECTRON SPINS OF MICELLIZED RADICAL PAIRS, Chemical physics, 199(2-3), 1995, pp. 119-127
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics → ACNP
ISSN journal
03010104
Volume
199
Issue
2-3
Year of publication
1995
Pages
119 - 127
Database
ISI
SICI code
0301-0104(1995)199:2-3<119:AESMOT>2.0.ZU;2-S
Abstract
An exact analytical calculation of the dipole-dipole relaxation rate o f electron spins in a micelle is proposed for a spherically symmetrica l model of radical diffusion. The results obtained are close to the Mo nte Carlo numerical calculations of the dipole-dipole relaxation. The results for the dipole-dipole relaxation in homogeneous solutions, ada pted to micellized radical pairs, approximate well our calculations fo r intermediate and large micelles at all magnetic fields.