Nb. Mikheev et al., ON THE POSSIBILITY OF REDUCTION OF AC3-ETHANOLIC SOLUTIONS OF BIVALENT SAMARIUM( TO AC2+ IN AQUEOUS), Radiochemistry, 37(4), 1995, pp. 297-299
In view of contradictory data on the existence of AC(2+) in aqueous so
lutions, the possibility of actinium reduction was examined in aqueous
-ethanolic solutions in which bivalent f-elements are more stable than
in aqueous media. In the presence of bivalent samarium (E(Sm3+/Sm2+)(
O) = -1.5 V) Ac(III) is not reduced to Ac(II). These results disagree
with the previously published data on the radiopolarographic generatio
n of Ac(II) in aqueous solutions.