ON THE POSSIBILITY OF REDUCTION OF AC3-ETHANOLIC SOLUTIONS OF BIVALENT SAMARIUM( TO AC2+ IN AQUEOUS)

Citation
Nb. Mikheev et al., ON THE POSSIBILITY OF REDUCTION OF AC3-ETHANOLIC SOLUTIONS OF BIVALENT SAMARIUM( TO AC2+ IN AQUEOUS), Radiochemistry, 37(4), 1995, pp. 297-299
Citations number
10
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
10663622
Volume
37
Issue
4
Year of publication
1995
Pages
297 - 299
Database
ISI
SICI code
1066-3622(1995)37:4<297:OTPORO>2.0.ZU;2-9
Abstract
In view of contradictory data on the existence of AC(2+) in aqueous so lutions, the possibility of actinium reduction was examined in aqueous -ethanolic solutions in which bivalent f-elements are more stable than in aqueous media. In the presence of bivalent samarium (E(Sm3+/Sm2+)( O) = -1.5 V) Ac(III) is not reduced to Ac(II). These results disagree with the previously published data on the radiopolarographic generatio n of Ac(II) in aqueous solutions.