S. Morad et al., DIAGENESIS OF A MIXED SILICICLASTIC EVAPORITIC SEQUENCE OF THE MIDDLEMUSCHELKALK (MIDDLE TRIASSIC), THE CATALAN COASTAL RANGE, NE SPAIN/, Sedimentology, 42(5), 1995, pp. 749-768
The Middle Muschelkalk (Middle Triassic) of the Catalan Coastal Range
(north-east Spain) comprises sandstone, mudstone, anhydrite and minor
carbonate layers. Interbedded sandstones and mudstones which are domin
ant in the north-eastern parts of the basin are terminal alluvial fan
deposits. South-westward in the basin, the rocks become dominated by i
nterbedded evaporites and mudstones deposited in sabkha/mudflat enviro
nments. The diagenetic and pore water evolution patterns of the Middle
Muschelkalk suggest a strong facies control. During eodiagenesis, for
mation of microdolomite, anhydrite, baryte, magnesite, K-feldspar and
mixed-layer chlorite/smectite was favoured within and adjacent to the
sabkha/mudflat facies, whereas calcite, haematite, mixed-layer illite/
smectite and quartz formed mainly in the alluvial facies. Low delta(18
)O(SMOW) values for microdolomite (+23.7 to +28.4%) of and K-feldspar
overgrowths (+17.3 to +17.7 parts per thousand) suggest either low-tem
perature, isotopic disequilibrium or precipitation from low-O-18 porew
aters. Low-O-18 waters might have developed, at least in part, during
low-temperature alteration of volcanic rock fragments. During mesodiag
enesis, precipitation of quartz overgrowths and coarse dolomite occurr
ed in the alluvial sandstones, whereas recrystallization of microdolom
ite was dominant in the sabkha/mudflat facies. The isotopic compositio
ns of these mesogenetic phases reflect increasing temperature during b
urial. Upon uplift and erosion, telogenetic calcite and trace haematit
e precipitated in fractures and replaced dolomite. The isotopic compos
ition of the calcite (delta(18)O(SMOW) = +21.5 to = +25.6 parts per th
ousand; delta(13)C = -7.7 to -5.6 parts per thousand) and presence of
haematite indicate infiltration of meteoric waters.