ALPHA-HYDROGEN ELIMINATION IN SOME CARBOHYDRATE TRIFLATES

Authors
ELNEMR A TSUCHIYA T
Citation
A. Elnemr et T. Tsuchiya, ALPHA-HYDROGEN ELIMINATION IN SOME CARBOHYDRATE TRIFLATES, Tetrahedron letters, 36(42), 1995, pp. 7665-7668
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
42
Year of publication
1995
Pages
7665 - 7668
Database
ISI
SICI code
0040-4039(1995)36:42<7665:AEISCT>2.0.ZU;2-J
Abstract
In some carbohydrate triflates, treatment with MeLi (or BuLi) in ether caused alpha-hydrogen elimination initially, then the resulting carba nion is stabilized to give either C-methyl(or butyl)-hydroxy derivativ es or unsaturated products.