The envelope-function theorem is considered in the limit that electron
energy far exceeds that of the characteristic height of the potential
array which, in turn, is comprised of a slowly varying component and
smaller amplitude rapidly varying component. Working in the nearly-fre
e-electron model, it is found that ''new'' energies and wave functions
at band edges are those related to the slowly varying component of th
e potential. Wave functions related to the rapidly varying potential c
omponent average to zero over a small function of a primitive cell. Th
ese properties comprise the envelope-function theorem relevant to high
-energy charge carriers passing through a quantum well array. (C) 1995
American Institute of Physics.