Jf. Groves et al., DIRECTED VAPOR-DEPOSITION OF AMORPHOUS AND POLYCRYSTALLINE ELECTRONICMATERIALS - NONHYDROGENATED A-SI, Journal of the Electrochemical Society, 142(10), 1995, pp. 173-175
A novel directed vapor deposition (DVD) process for creating amorphous
and polycrystalline electronic materials is reported. Initial experim
ental results for DVD of nonhydrogenated a-Si indicate that growth rat
es at least between 0.02 and 1.0 mu m/min can be achieved. In this pro
cess, evaporated silicon is efficiently entrained in a previously form
ed low pressure supersonic He jet. The silicon is evaporated using a h
igh energy, high voltage, electron beam. The collimated jet of He entr
ained with silicon is used to deposit thin films of a-Si at room tempe
rature on glass substrates. Initial TEM microstructure analysis and op
tical absorption analysis is presented.