COPPER(I) CARBONYL COMPLEX OF A TRIFLUOROMETHYLATED TRIS(PYRAZOLYL)BORATE LIGAND

Authors
DIAS HVR LU HL
Citation
Hvr. Dias et Hl. Lu, COPPER(I) CARBONYL COMPLEX OF A TRIFLUOROMETHYLATED TRIS(PYRAZOLYL)BORATE LIGAND, Inorganic chemistry, 34(21), 1995, pp. 5380
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
21
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:21<5380:CCCOAT>2.0.ZU;2-H
Abstract
Synthesis and characterization of the copper(I)carbonyl complex of flu orinated tris(pyrazolyl)borate ligand, [HB(3,5-(CF3)(2)Pz)(3)](-) (whe re HB(3,5-(CF3)(2)Pz)(3) = ydrotris(3,5-bis(trifluoromethyl)pyrazolyl) borate) is reported. The CO stretching frequency of the [HB-(3,5-(CF3) (2)Pz)(3)]CuCO is one of the highest observed for a structurally chara cterized copper complex.