MOLECULE-BASED MAGNETS - FERROMAGNETIC AND ANTIFERROMAGNETIC INTERACTIONS IN NICKEL(II) CYCLOHEXASILOXANOLATE SANDWICH COMPLEXES

Authors
CORNIA A FABRETTI AC GATTESCHI D PALYI G RENTSCHLER E SHCHEGOLIKHINA OI ZHDANOV AA
Citation
A. Cornia et al., MOLECULE-BASED MAGNETS - FERROMAGNETIC AND ANTIFERROMAGNETIC INTERACTIONS IN NICKEL(II) CYCLOHEXASILOXANOLATE SANDWICH COMPLEXES, Inorganic chemistry, 34(21), 1995, pp. 5383
Citations number
58
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
21
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:21<5383:MM-FAA>2.0.ZU;2-Y
Abstract
Ferromagnetic exchange-coupling interactions mediated by siloxanolate ligands have been detected in the two nickel(II) nanoscale clusters Na -2[(PhSiO(2))(6)Na4Ni4(OH)(2)(O-2-SiPh)(6)]. 16Bu(n)OH (1) and Na-2[(P hSiO(2))(6)Ni-6(O(2)SiPh)(6)Cl]. 12CH(3)OH . H2O (2), which qualify as interesting precursors for new molecule-based magnetic materials. Com plex 1 has an S = 4 spin ground state, whereas complex 2 has an S = 0 spin ground state. due to the presence of additional antiferromagnetic interactions through the encapsulated mu(6)-chloride ion.