COORDINATION-COMPLEXES OF BIS(TRIPHENYLPHOSPHINE) COPPER(I) CARBONATEAND BICARBONATE

Authors
DARENSBOURG DJ HOLTCAMP MW KHANDELWAL B REIBENSPIES JH
Citation
Dj. Darensbourg et al., COORDINATION-COMPLEXES OF BIS(TRIPHENYLPHOSPHINE) COPPER(I) CARBONATEAND BICARBONATE, Inorganic chemistry, 34(21), 1995, pp. 5390
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
21
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:21<5390:COBCC>2.0.ZU;2-Y
Abstract
The solid-state structures of dimeric bis(triphenylphosphine)copper(I) carbonate and bicarbonate have been determined by X-ray crystallograp hy. The bicarbonate complex possesses an uncommon mode of carbonate or carboxylate binding. That is, the two Cu(I) ions are bridged by two o xygen atoms, one from each of two bicarbonate ligands. This bonding in teraction is complemented by strong intermolecular hydrogen-bonding.