K. Bhanumurthy et al., AN EMPIRICAL THERMODYNAMIC MODEL TO PREDICT THE FIRST-PHASE FORMATIONIN THIN-FILM BINARY DIFFUSION COUPLES, Transactions of the Indian Institute of Metals, 48(3), 1995, pp. 193-196
An empirical thermodynamic model for predicting the first phase format
ion in binary diffusion couples is described. The model suggests a sui
table modification to the existing effective heat of formation model (
EHF) by quantitatively describing a congruency factor. The model predi
cts correctly the phase formation in several silicides, germinides and
metal-metal binary systems, which otherwise could not be explained by
EHF model.