STRUCTURE OF A PCU-DERIVED PINACOL FORMED VIA SODIUM-PROMOTED REDUCTIVE DIMERIZATION OF LO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE-8,11-DIONE MONOETHYLENE KETAL

Authors
BOTT SG MARCHAND AP RAJAGOPAL D
Citation
Sg. Bott et al., STRUCTURE OF A PCU-DERIVED PINACOL FORMED VIA SODIUM-PROMOTED REDUCTIVE DIMERIZATION OF LO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE-8,11-DIONE MONOETHYLENE KETAL, Journal of chemical crystallography, 25(8), 1995, pp. 517-520
Citations number
15
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
25
Issue
8
Year of publication
1995
Pages
517 - 520
Database
ISI
SICI code
1074-1542(1995)25:8<517:SOAPPF>2.0.ZU;2-F
Abstract
The pinacol resulting from sodium promoted reductive coupling of o[5.4 .0.0(2,6).O-3,O-10.0(5,9)]undecane-8,11-dione monoethylene ketal posse sses a conformation, dictated by intramolecular hydrogen bonding, that lies midway between eclipsed and staggered. The C-C and C-O distances in the pinacol unit are, respectively, longer and shorter than usual, and all parameters are as expected.