M. Somei et al., PREPARATIONS OF TRYPTAMINE-4,5-DIONES, AND THEIR DIELS-ALDER AND NUCLEOPHILIC-ADDITION REACTIONS, Heterocycles, 41(10), 1995, pp. 2157-2160
Syntheses of Nb-acetyltryptamine-4,5-dione and (+/-)-Nb-acetyltryptoph
an-4,5-dione methyl ester are reported. They were excellent dienophile
s as well as good electrophiles, and produced 6,7-disubstituted indole
s in Diels-Alder reaction and various 7-substituted indoles with nucle
ophiles.