It was found that doping with tellurium affects the solubility of oxyg
en in ZnSe[Te] single crystals grown from melts. This factor determine
s the optical properties of the crystals. It was shown that, depending
on the ratio [Te]/[O], different types of O-Te complexes-intrinsic po
int defects-can form in the presence of an excess of zinc. The nature
of the luminescence centers in ZnSe[Te] (O, Zn) (BE, 470-490, 550, 635
, 720, and 1300 nm bands) is discussed on the basis of the results of
the investigation of the optical properties of the microstructure, tak
ing into account the equilibrium of the intrinsic point defects. (C) 1
995 American Institute of Physics.