REDOX PROPERTIES OF TRINUCLEAR IRIDIUM MU(3)-OXOCARBOXYLATES IN ACETONITRILE SOLUTIONS

Authors
BELYAEV AN SIMANOVA SA BASHMAKOV VI BURMISTROVA NM
Citation
An. Belyaev et al., REDOX PROPERTIES OF TRINUCLEAR IRIDIUM MU(3)-OXOCARBOXYLATES IN ACETONITRILE SOLUTIONS, Russian journal of applied chemistry, 67(12), 1994, pp. 1797-1799
Citations number
3
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
12
Year of publication
1994
Part
2
Pages
1797 - 1799
Database
ISI
SICI code
1070-4272(1994)67:12<1797:RPOTIM>2.0.ZU;2-3
Abstract
The influence of an R substituent (CH3, CH2Cl, CCl3) in bridging ligan ds (mu-O(2)CR) on the stability of the highly oxidized state Ir-3(III, III,IV) in trinuclear iridium mu(3)-oxocarboxylates has been studied b y cyclovoltammetry and potentiostatic coulometry in acetonitrile solut ion in the 0-1.5 V potential range. The stability decreases with incre ase in electron acceptor power of R in the order CH3 > CH2Cl > CCl3.