A STUDY OF THE NEGATIVE-ION FABMS OF TRIS(PERFLUOROPHENYL)PHOSPHINE AND RELATED-COMPOUNDS - MATRIX EFFECTS

Authors
SARASWATHI M MILLER JM JONES TRB
Citation
M. Saraswathi et al., A STUDY OF THE NEGATIVE-ION FABMS OF TRIS(PERFLUOROPHENYL)PHOSPHINE AND RELATED-COMPOUNDS - MATRIX EFFECTS, Canadian journal of chemistry, 73(8), 1995, pp. 1321-1328
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
73
Issue
8
Year of publication
1995
Pages
1321 - 1328
Database
ISI
SICI code
0008-4042(1995)73:8<1321:ASOTNF>2.0.ZU;2-4
Abstract
The mass spectra of tris(perfluorophenyl)phosphine obtained under nega tive ion Fast Atom Bombardment conditions showed formation of an unusu al ion at m/z 397 attributed to ((C6F5)(2)PO2)(-). The matrix effects involved in this reaction are discussed. Negative ion FAB spectra of t ris(perfluorophenyl)arsine and tris(perfluorophenyl)stibine are also r eported.