EASY PREPARATION OF ENOXYSILANES FROM ALDEHYDES AND KETONES CATALYZEDBY SAMARIUM DIIODIDE

Authors
HYDRIO J VANDEWEGHE P COLLIN J
Citation
J. Hydrio et al., EASY PREPARATION OF ENOXYSILANES FROM ALDEHYDES AND KETONES CATALYZEDBY SAMARIUM DIIODIDE, Synthesis, (1), 1997, pp. 68
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
1
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):1<68:EPOEFA>2.0.ZU;2-O
Abstract
Ketones and alpha-substituted aldehydes are converted to trimethylsily l enol ethers by reaction with the trimethylsilyl ketene acetal of met hyl isobutyrate in dichloromethane in presence of a catalytic amount o f samarium diiodide.