THE EFFECT OF OROGRAPHY ON WET DEPOSITION IN AN INDUSTRIAL-AREA

Two field experiments were carried out to observe the variation in wet deposition of ions caused by orography in a polluted region of the UK . The site chosen was Winter Hill which lies on the edge of the indust rialised Mersey valley. Rain and cloud samples were collected daily an d chemically analysed. Synoptic and meteorological data were used to c lassify individual rain events as frontal or convective. For the front al events the altitude related increase in wet deposition was found to be entirely caused by the seeder-feeder mechanism (the scavenging of cap cloud by rain from above). The concentration of marine ions in the water scavenged from the cap cloud was found to be between five and s ix times that in the seeder rain whereas for anthropogenically produce d ions it was about twice as great. The efficiency of the seeder-feede r mechanism is correspondingly affected. Convective events accounted f or less than a quarter of the rainfall volume. However, this contained over half of the deposition of marine ions in the valley. Deposition of anthropogenically produced ions in convective events was small prob ably due to a lack of convection over land. A small decrease in deposi tion with altitude was observed for these events although this is expe cted to be a highly local effect. It is concluded that reliable predic tions of the wet deposition of non-marine ions can be made on the basi s of the seeder-feeder effect for northern and western regions of the UK. Elsewhere in the UK and for much of continental Europe wet deposit ion from convective rain should be taken into account.