THERMODYNAMIC ANALYSIS ON THE ROLE OF HYDROGEN IN ANODIC STRESS-CORROSION CRACKING

Authors
Citation
L. Qiao et X. Mao, THERMODYNAMIC ANALYSIS ON THE ROLE OF HYDROGEN IN ANODIC STRESS-CORROSION CRACKING, Acta metallurgica et materialia, 43(11), 1995, pp. 4001-4006
Citations number
31
Categorie Soggetti
Material Science","Metallurgy & Metallurigical Engineering
ISSN journal
09567151
Volume
43
Issue
11
Year of publication
1995
Pages
4001 - 4006
Database
ISI
SICI code
0956-7151(1995)43:11<4001:TAOTRO>2.0.ZU;2-T
Abstract
A synergistic effect of hydrogen and stress on a corrosion rate was an alyzed with thermodynamics. The results showed that an interaction of stress and hydrogen could increase the corrosion rate remarkably. Stre ss corrosion cracking (SCC) of austenitic stainless steel (ASS) was in vestigated in boiling chloride solution to confirm the analysis. Hydro gen could be introduced into the specimen and concentrated at the crac k tip during SCC in boiling LiCl solution (143 degrees C). The concent rating factor is about 3 which is consistent with calculated results a ccording to stress induced diffusion.