SYNTHESIS, CHARACTERIZATION, AND SOLID-STATE STRUCTURES OF THE 14-ELECTRON OPEN METALLOCENES M[1,5-(ME(3)SI)(2)C5H5](2) (M=TI OR ZR)

Authors
GEDRIDGE RW ARIF AM ERNST RD
Citation
Rw. Gedridge et al., SYNTHESIS, CHARACTERIZATION, AND SOLID-STATE STRUCTURES OF THE 14-ELECTRON OPEN METALLOCENES M[1,5-(ME(3)SI)(2)C5H5](2) (M=TI OR ZR), Journal of organometallic chemistry, 501(1-2), 1995, pp. 95-100
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
501
Issue
1-2
Year of publication
1995
Pages
95 - 100
Database
ISI
SICI code
0022-328X(1995)501:1-2<95:SCASSO>2.0.ZU;2-O
Abstract
Reactions of titanium(II) or zirconium(IV) chlorides with two or four equivalents of K[1,5-(Me(3)Si)(2)C5H5], respectively, lead to the diam agnetic 14-electron M[1,5-(Me(3)Si)(2)C5H5](2) complexes. Both have be en characterized analytically, spectroscopically, and through single c rystal X-ray diffraction studies.