SYNTHESIS AND CRYSTAL-STRUCTURE OF N,S)-1-METHYLIMIDAZOLINE-2-THIONATO)-TETRAZINC(II)

Authors
CASTRO R GARCIAVAZQUEZ JA ROMERO J SOUSA A DACHANG Y ZUBIETA J
Citation
R. Castro et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF N,S)-1-METHYLIMIDAZOLINE-2-THIONATO)-TETRAZINC(II), Inorganica Chimica Acta, 237(1-2), 1995, pp. 143-146
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
237
Issue
1-2
Year of publication
1995
Pages
143 - 146
Database
ISI
SICI code
0020-1693(1995)237:1-2<143:SACON>2.0.ZU;2-M
Abstract
Electrochemical oxidation of zinc in a solution of 1-methylimidazoline -2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)(6)] whose cryst al structure has been determined by X-ray diffraction. This compound c ontains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.